II. Monitoring and Releases of POPs

by Mr. Gábor KOVÁCS

 

Introduction

This paper provides the second part of the Hungarian national presentation and, therefore, it compliments the paper prepared by Dr. Zoltán ADAMIS and entitled "The Regulation and Management of POPs". The two together, they describe the present situation as far as the emissions on POPs and their management in Hungary are concerned.

In 1997, the Ministry of the Environment and Regional Policy requested the Institute for Environment Protection to complete a background paper, which was considered as a Hungarian contribution to the preparation of international/regional agreements on Heavy Metals and Persistent Organic Pollutants.

This report contains both general information and data inventory with regard to the use and emissions detailed on each POP compound in Hungary. The identification of POPs was performed by the TNO Institute of Environmental Science, Energy Research and Process Innovation in accordance with the "Technical Paper to the OSPARCOM-HELICOM-UNECE Emission Inventory of Heavy Metals and Persistent Organic Pollutants". The structure of substances, methods of calculations and emission factors are consistent with the above-mentioned Technical Paper and the international questionaries. Due to the fact that the production and use of most POP compounds is banned or severely restricted, the total annual amounts refer to the emissions of by-products from several processes.

PAH (Polycyclic Aromatic Hydrocarbons)

For PAH, the trend of total annual emissions was the decrease from 137.1 kt to 61.7 kt between 1980 and 1996 (Chart 1, Table 1). Within the total emission, the pyrogeneous emission trend was similar. The amount changed from 105 kt to 49 kt.

There was a crucial point in the country industrial development: the coke production was totally liquidated in 1993. Practically only one foundry is still operating, namely in the primary aluminium production (Table 1-2).

Of the total country emission, 79% fall into the category of pyrogeneous emissions and, within the latter, emissions of households take 60 %.

Taking into account the 6 Borneff PAH compounds, it was found out, that the most important factor was the fluoranthene emission which represented 54.4 % of the total (Chart 2, Table 3).

PCBs (Polychlorinated Biphenyls)

The trend of PCBs emissions was similarly on the decrease (Chart 3). Between 1980 and 1996, the total emission was reduced from 180.4 kg to 97.6 kg. This resulted mainly from a considerable decrease in the pyrogeneous emission which was reduced from 158.9 kg to 89 kg during the same time period (Table 4).

In the case of PCBs, the most important point is that the pyrogeneous emission amounts to 91 % of the total emission. The largest source is the power plants. They produce about 55-60 % of the total pyrogeneous emission. Two other significant factors contributing to the pyrogeneous emission originate from combustions in households and industry.

In 1996, the PCB emission in Hungary was 97.6 kg and consisted of by-products only (Table 4, total). The major emission sources were the use of fossile fuel and industrial processes.

DIOXINS/FURANS

The total emission of DIOXINS decreased from 184.9 g TEQ to 103.5 g TEQ between 1980 and 1996 (Chart 4, Table 5). The major sources are as follows:

% of the total

  • incineration 44.9

  • households firing 24.7

  • power plant combustion 13.2

  • The pyrogeneous emission was reduced from 122,6 g TEQ to 49,7 g TEQ during the above-mentioned time interval. It should be noted that, in 1996, the pyrogeneous emission was only about 48 % of the total emission. The major part of the pyrogeneous DIOXIN emission was produced by solid fuel firing and combustion.

    HCB (Hexachlorobenzene)

    In the case of HCB and PCP, only the emission of incineration of municipal waste could be measured and calculated. At present, only one municipal waste incinerator exists in Hungary (Table 6).

    Pesticides

    Furthermore, Table 7 provides some data about pesticides containing Lindane and Endosulfan (use and emission). In addition to the existing national legislation/regulations dealing with chemicals/pesticides, other relevant laws as well as related Action Programmes aimed at reducing/eliminating of the emissions are currently under preparation in Hungary.

    TABLE 1 : Pyrogeneous and Total PAH (6 Borneff species) emissions in accordance with major sectors (in tonnes)

     

     

     

     

     

    1980

    1985

    1990

    1991

    1992

    1993

    1994

    1995

    1996

    Households

    81,521

    102,907

    74,285

    76,637

    48,101

    48,911

    42,757

    39,694

    36,427

    Services

    9,235

    9,415

    4,165

    9,451

    6,884

    4,188

    5,737

    3,400

    2,850

    Power plants

    0,144

    0,189

    0,065

    0,125

    0,167

    0,219

    0,205

    0,204

    0,169

    District heat

    0,235

    0,159

    0,097

    0,106

    0,110

    0,124

    0,112

    0,089

    0,043

    Agriculture

    2,870

    3,978

    2,177

    2,532

    2,040

    2,427

    2,273

    3,039

    2,737

    Industry

    3,725

    3,117

    1,823

    1,516

    1,295

    1,233

    1,409

    1,233

    1,255

    Road transport

    7,667

    7,727

    6,680

    5,803

    5,948

    5,719

    5,963

    5,785

    5,490

    Pyrogeneous total

    105,398

    127,493

    89,292

    96,170

    64,546

    62,820

    58,457

    53,446

    48,972

    Coke production

    3,169

    1,973

    2,184

    2,181

    0,436

    0,000

    0,000

    0,000

    0,000

    Primary Al prod.

    29,128

    28,514

    29,016

    24,445

    20,616

    16,446

    11,968

    12,354

    12,740

    Total

    137,695

    157,980

    120,492

    122,796

    85,597

    79,267

    70,425

    65,800

    61,712

     

     

    TABLE 2 : The six Borneff PAH emissions of primary Al production (in tonnes).

     

     

     

     

     

     

    1980

    1985

    1990

    1991

    1992

    1993

    1994

    1995

    1996

    benz(a)pyrene

    4,225

    4,136

    4,209

    3,546

    2,990

    2,386

    1,736

    1,792

    1,848

    benzo(ghi)perylene

    0,755

    0,739

    0,752

    0,633

    0,534

    0,426

    0,310

    0,320

    0,330

    benzo(k)fluoranthene

    3,032

    2,968

    3,020

    2,544

    2,146

    1,712

    1,246

    1,286

    1,326

    fluoranthene

    17,708

    17,335

    17,640

    14,861

    12,533

    9,998

    7,276

    7,510

    7,745

    Indeno(1,2,3-cd)pyrene

    0,377

    0,369

    0,376

    0,317

    0,267

    0,213

    0,155

    0,160

    0,165

    benzo(b)fluorantene

    3,032

    2,968

    3,020

    2,544

    2,146

    1,712

    1,246

    1,286

    1,326

    Total

    29,128

    28,514

    29,016

    24,445

    20,616

    16,446

    11,968

    12,354

    12,740

     

     

     

    TABLE 3 : Total PAH emissions in accordance with the six Borneff species (in tonnes)

     

     

     

     

     

    1980

    1985

    1990

    1991

    1992

    1993

    1994

    1995

    1996

    benz(a)pyrene

    14,452

    16,230

    12,875

    12,972

    9,035

    8,181

    7,107

    6,674

    6,292

    benzo(ghi)perylene

    11,574

    13,453

    9,911

    10,576

    7,515

    7,245

    6,772

    6,075

    5,563

    benzo(k)fluoranthene

    8,889

    10,027

    7,957

    7,884

    5,494

    4,920

    4,187

    4,013

    3,832

    fluoranthene

    73,653

    83,244

    64,306

    64,648

    46,202

    42,555

    37,844

    35,629

    33,580

    Indeno(1,2,3-cd)pyrene

    12,796

    15,931

    11,106

    11,832

    7,067

    6,741

    5,936

    5,427

    5,008

    benzo(b)fluorantene

    16,330

    19,095

    14,337

    14,884

    10,283

    9,624

    8,580

    7,982

    7,437

    Total

    137,695

    157,980

    120,492

    122,796

    85,597

    79,267

    70,425

    65,800

    61,712

     

    TABLE 4 : Pyrogeneous and Total PCB emissions in accordance with major sectors (in kg.)

     

     

     

     

    1980

    1985

    1990

    1991

    1992

    1993

    1994

    1995

    1996

    Households

    30,2

    37,8

    27,9

    27,9

    17,7

    16,7

    13,9

    12,7

    11,6

    Services

    5,5

    5,1

    3,0

    4,5

    3,2

    2,0

    2,7

    1,9

    1,6

    Power plants

    67,6

    59,9

    49,2

    48,6

    52,8

    53,0

    50,7

    52,6

    53,8

    District heat

    2,6

    1,7

    1,0

    1,1

    1,1

    1,3

    1,1

    0,9

    0,3

    Agriculture

    5,2

    4,7

    3,2

    2,7

    1,8

    2,0

    2,0

    2,1

    2,1

    Industry

    37,6

    30,6

    19,0

    15,8

    14,0

    13,0

    14,8

    12,2

    12,4

    Road transport

    10,3

    8,4

    9,2

    8,2

    8,0

    8,0

    7,8

    7,6

    7,1

    Pyrogeneous total

    158,9

    148,2

    112,5

    108,7

    98,6

    96,0

    93,1

    90,0

    89,0

    From landfills

    0,1

    0,1

    0,1

    0,1

    0,1

    0,1

    0,1

    0,1

    0,1

    Incineration

    0,3

    0,3

    0,3

    0,3

    0,3

    0,3

    0,3

    0,3

    0,3

    Sintering

    7,6

    7,4

    6,0

    3,9

    3,1

    3,5

    3,9

    3,9

    1,9

    Crude steel production

    13,6

    13,1

    10,7

    6,9

    5,5

    6,3

    7,0

    6,7

    6,3

    Total

    180,4

    169,1

    129,5

    119,9

    107,6

    106,2

    104,3

    101,0

    97,6

     

    TABLE 5 : Pyrogeneous and Total DIOXINs emissions in accordance with major sectors (in mgTEQ)

     

     

     

     

    1980

    1985

    1990

    1991

    1992

    1993

    1994

    1995

    1996

    Households

    70713,3

    93980,8

    66173,5

    66148,7

    34785,4

    34789,8

    27417,9

    27188,8

    25541,8

    Services

    10777,8

    11015,6

    4834,2

    11094,8

    8083,4

    4913,4

    6736,1

    4150,3

    3484,2

    Power plants

    17676,9

    15132,5

    13209,7

    12522,6

    13347,4

    12978,3

    12448,4

    13074,8

    13685,8

    District heat

    3748,1

    2587,3

    1634,0

    1787,8

    1864,8

    2097,9

    1869,4

    1475,7

    20,9

    Agriculture

    3866,7

    4776,4

    2756,0

    2968,5

    2309,3

    2714,8

    2556,4

    3293,0

    3006,3

    Industry

    10437,6

    8511,1

    5265,5

    4392,7

    3885,0

    3607,2

    4111,4

    3402,1

    3457,6

    Road transport

    5337,8

    977,8

    880,4

    701,8

    613,2

    524,1

    421,3

    271,3

    199,4

    Pyrogeneous total

    122558,2

    136981,5

    94753,3

    99617,0

    64888,4

    61625,5

    55560,9

    52856,1

    49396,0

    Incineration

    46500,0

    46500,0

    46500,0

    46500,0

    46500,0

    46500,0

    46500,0

    46500,0

    46500,0

    Sintering process

    15879,0

    15381,5

    12500,0

    8142,0

    6501,0

    7395,5

    8171,5

    8199,5

    4000

    Secondary Cu process

    n.a.

    n.a.

    1080,0

    720,0

    640,0

    620,0

    720,0

    700,0

    760

    Electric arc furnace

    n.a.

    15785,0

    12530,0

    3920,0

    2240,0

    3430,0

    2555,0

    3955,0

    2870,0

    Total

    184937,2

    214648,0

    167363,3

    158899,0

    120769,4

    119571,0

    113507,4

    112210,6

    103526,0

    TABLE 6 : POPs emissions from solvent and chemical use (in kilotonnes)

     

     

     

     

    1980

    1985

    1990

    1991

    1992

    1993

    1994

    1995

    1996

    HCB from incineration

    0,62

    0,62

    0,62

    0,62

    0,62

    0,62

    0,62

    0,62

    0,62

    PCP from incineration

    0,037

    0,037

    0,037

    0,037

    0,037

    0,037

    0,037

    0,037

    0,037

    PCP

    0,340

    0,337

    PER

    n.a.

    n.a.

    n.a.

    n.a.

    n.a.

    n.a.

    n.a.

    n.a.

    TCE

    n.a.

    0,54

    0,68

    0,58

    0,444

    0,29

    0,186

    0,09

    0

    TCB

    n.a.

    n.a.

    n.a.

    n.a.

    n.a.

    n.a.

    n.a.

    n.a.

    TRI

    n.a.

    n.a.

    n.a.

    n.a.

    n.a.

    n.a.

    n.a.

    n.a.

    TCM

    n.a.

    0,7

    0,485

    0,32

    0,2

    0,124

    0,029

    0,016

    0

    Total

    0,657

    1,897

    2,162

    1,557

    1,301

    1,071

    1,209

    0,763

    0,657

    TRI, TCE and TCM banned from 1 of January 1996.

     

    PCP highly restricted.
    HCB = hexachlorobenzene
    PCP = pentachlorophenol
    PER = tetrachloroethylene

     

    TCE = trichloroethane
    TCB = trichlorobenzene
    TRI = trichloroethylene
    TCM = tetrachloromethane

     

    TABLE 7 : Lindane (L) and Endosulfan (E) containing pesticides use with special permission (in tonnes)

     

     

     

     

    1990

    1991

    1992

    1993

    1994

    1995

    1996

    TERRA-TOX 80g/l L and 200g/l E.

    0

    1

    0,2

    7,7

    13,3

    5

    40

    THIODAN 35 EC 35%E

    188,2

    98,2

    65

    78

    66,2

    104,3

    78

    THIODAN ULV 25%E

    10,7

    2,5

    0

    0

    2,4

    0

    0

    THIONEX 35 EC 35%E

    12,7

    13,6

    0

    9

    25

    50

    45,5

    LINDAFOR 75%L

    16,5

    0

    0

    0

    0

    0

    0

    Use (in tonnes)

    1990

    1991

    1992

    1993

    1994

    1995

    1996

    Lindane

    12,375

    0,080

    0,016

    0,616

    1,064

    2,200

    3,200

    Endosulfan

    72,990

    39,955

    22,790

    31,990

    35,180

    55,005

    51,225

                   

    POPs emissions (in tonnes)

    1990

    1991

    1992

    1993

    1994

    1995

    1996

    from Lindane

    9,281

    0,060

    0,012

    0,462

    0,798

    1,650

    2,400

    from Endosulfan

    25,547

    13,984

    7,977

    11,197

    12,313

    19,252

    17,929