19. Control and Management of PCBs in Oil and Gas Industry
by Mr. M. Ponnambalam
The supply and use of PCB containing equipment such as transformers are
administratively prohibited in ADNOC and its Group of Companies. All suspected equipment
has been sampled and analyzed for the presence of PCB at or above 50 mg/kg, the control
limit for transformer oils. Action has been taken by the concerned operations in the oil
and Gas Industry to phase out those equipment containing PCBs even at levels as low as
50mg/kg.
PCBs
PCBs unique properties led to a wide range of industrial applications.
The same properties made it harmful to the environment.
PCB is:
- Bioaccumulative, persistent and potentially toxic.
- Very resistant to chemical and biochemical degradation, and therefore also persists in
the environment.
- Soluble in fats and oils, and therefore also tends to accumulate in the fatty tissues of
living organisms.
PCB has been:
- Widely dispersed into the environment at low concentrations.
- Assimilated into the food chain. Significant levels appear in the body fats of predatory
birds, and of sea mammals such as seals, otters and dolphins.
- Reliably linked with the inability of such animals to reproduce successfully, with birth
defects in young, and with their deaths through immune deficiency.
- Some of the equipment contains PCB, or may contain PCB or may contain PCB; a site is or
may be contaminated with PCB.
- Plan a sample survey consider whether you will do a full survey if the sample
survey shows that you have some PCB equipment or PCB waste.
- Will the extra information be worth the cost of the survey?
- Because of their fire resistance, high resistivity, chemical dielectric strength and low
power factor they were particularly used in the electrical industry.
- In electricity generating and distribution, PCB was mainly a capacitor impregnant and
transformer coolant.
- Dilluent solvents such as tri- and tetrachlorbenzene were often used in conjunction with
PCB in transformer fluids to reduce viscosity.
PCB in the environment
- PCB has been implicated in population declines of seals in the Baltic Sea and Wadden
Sea.
- PCB in the Marine Environment.
- The highest levels of PCB when observed was attributed to dockyard operations
where PCB is used in transformers or as flame retardant in hydraulic oils.
PCBs Industrial Accidents
- Contamination rice bran oil with commercial PCB mixture
- Kanechlor 400 more than 1600 victims YU-Cheng (Taiwan, 1979)
- PCB Poisoning incident more than 2000 victims
PCBs Chemical Hazardous to Health and Requiring
Risk assessment to evaluate risk to health and environment,
manage and control exposure (monitoring-exposure; environmental health surveillance
Is it appropriate? (information, instruction and training on what should be done.
- Hazardous waste
PCBs Legislative Initiatives and Provisions
The European Community (EC) has adopted a number of Directives aimed at
restricting he use of PCB and PCT.
EC Directives 76/769/EEC and 85/467/EEC
- Restricted the marketing of PCB
- Restricted the use of PCB to and in closed systems
- Defined the threshold concentration of PCB or PCT in a mixture, including waste oil.
Above the threshold the restrictions would apply.
- Set targets for the eliminating of PCB and PCT, while allowing member states to exempt
any equipment could continue in use to the end of its service life.
- EC Directive 89/677/EEC, amending for the 8th time 76/769/EEC, changed the
concentration above which a preparation (mixture of substances) would be considered a PCB
or PCT and thus subject to control.
The UK regulations call such mixtures injurious substances:
- Waste Containing PCB and PCT was previously an injurious substances of its PCB or PCT
was 100 PPM.
- Waste Containing PCB and PCT is now an injurious substances of its PCB or PCT level is
50 PPM.
US EPA definition of PCB Containing Waste Limits the level to 50 PPM
PBC.
The equipment containing PCBs at or above 50 PPM are adequately labeled
with appropriate warming signs.
- They will be continued to used till the end of their service period.
- The spill of oils from suspect equipment has been and will be analyzed for the presence
of PCB for required follow up actions.
- Waste will be stored at our facility.